Rate enhancement for catalytic upgrading coal naphthas

Technical Report · Wed Jan 01 04:00:00 EST 1992

DOI:https://doi.org/10.2172/6698283· OSTI ID:6698283

Davis, B H

The removal of heteroatoms from naphtha using first row unsupported metal sulfide catalysts were completed. The maxima HDS activity, normalizing to the same weight of metal, is obtained for manganese sulfide while the minimum HDS activity is obtained for nickel sulfide. Chianelli et al. (1) reported that, for the first row transition metal sulfides, chromium sulfide has the highest activity for HDS of dibenzothiophene and manganese sulfide is the least active. The catalyst activity pattern of the first row transition metal sulfide for hydrodesulfurization of naphtha and dibenzothiophene is different. The maxima HDN activity, normalizing to the same weight of metal, is obtained for chromium sulfide and the minimum HDN activity is obtained for cobalt sulfide. The effect of substituents on the conversion of nitrogen compounds from the naphtha was also determined. The HDN conversion of alkyl-substituted pyridines and anilines are dominated by electronic effects rather than substituent effects. The effect of alkyl-substitution on the conversion of quinolines is relatively insignificant.

• Research Organization: Kentucky Univ., Lexington, KY (United States). Center for Applied Energy Research
• Sponsoring Organization: DOE; USDOE, Washington, DC (United States)
• DOE Contract Number: AC22-91PC91058
• OSTI ID: 6698283
• Report Number(s): DOE/PC/91058-T5; ON: DE93012457
• Country of Publication: United States
• Language: English

Related Subjects

01 COAL, LIGNITE, AND PEAT
010402* -- Coal
Lignite
& Peat-- Purification & Upgrading
010405 -- Coal
Lignite
& Peat-- Hydrogenation & Liquefaction
AMINES
ANILINE
AROMATICS
AZINES
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTIONS
CHROMIUM COMPOUNDS
CHROMIUM SULFIDES
COAL LIQUIDS
COBALT COMPOUNDS
COBALT SULFIDES
DATA
DENITRIFICATION
DESULFURIZATION
DISTILLATES
DOCUMENT TYPES
EXPERIMENTAL DATA
FLUIDS
HETEROCYCLIC COMPOUNDS
HYDROGENATION
INFORMATION
LIQUIDS
MANGANESE COMPOUNDS
MANGANESE SULFIDES
NAPHTHA
NICKEL COMPOUNDS
NICKEL SULFIDES
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
POLYCYCLIC SULFUR HETEROCYCLES
PROGRESS REPORT
PYRIDINES
REMOVAL
SULFIDES
SULFUR COMPOUNDS
TRANSITION ELEMENT COMPOUNDS