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Novel palladium(II)-catalyzed copolymerization of carbon monoxide with olefins

Journal Article · · J. Am. Chem. Soc.; (United States)
DOI:https://doi.org/10.1021/ja00376a053· OSTI ID:6697422
;

The catalyst, (Pd(CH/sub 3/CN)/sub 4/)(BF/sub 4/)/sub 2/.n-triphenylphosphine n = (1-3), demonstrated the capacity to mediate the copolymerization of CO with ethylene and other alkenes under very mild conditions. The reaction of ethylene (350 psi), dissolved in acetonitrile, and CO(350 psi) was performed at 25/sup 0/C for 1 d. The copolymerizations of CO(800 psi) with norbornadiene and norbornylene were performed at 60/sup 0/C. The structures of the copolymers were studied by NMR. 9 references, 1 figure.

Research Organization:
Pennsylvania State Univ., University Park
DOE Contract Number:
AC02-81ER10992
OSTI ID:
6697422
Journal Information:
J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 104:12; ISSN JACSA
Country of Publication:
United States
Language:
English

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Related Subjects

090121 -- Hydrocarbon Fuels-- Chemical Synthesis-- (1976-1989)
10 SYNTHETIC FUELS
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ACETONITRILE
ALKENES
BORON COMPOUNDS
BORON FLUORIDES
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
COMPARATIVE EVALUATIONS
COMPLEXES
COPOLYMERIZATION
COPOLYMERS
CYCLOALKENES
DATA
ETHYLENE
EXPERIMENTAL DATA
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
INFORMATION
LOW PRESSURE
MEDIUM PRESSURE
MEDIUM TEMPERATURE
NITRILES
NMR SPECTRA
NORBORNADIENE
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC POLYMERS
ORGANIC SOLVENTS
OXIDES
OXYGEN COMPOUNDS
PALLADIUM COMPLEXES
PHOSPHINES
PHOSPHORUS COMPOUNDS
POLYMERIZATION
POLYMERS
PRESSURE DEPENDENCE
SOLVENTS
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
TIME DEPENDENCE
TRANSITION ELEMENT COMPLEXES
YIELDS