Formation and disappearance of superoxide radicals in aqueous solutions. [79 references]
A literature review of superoxide radicals in aqueous solutions is presented covering the following: history; methods of formation of aqueous HO/sub 2//HO/sub 2//sup -/ by radiolysis and photolysis, electrolysis, mixing nonaqueous solutions into water, chemical reactions, enzymatic generation of O/sub 2//sup -/, and photosensitization; and properties of HO/sub 2//O/sub 2//sup -/ in aqueous solution, which cover spontaneous dismutation rates, pk and absorption spectra, catalyzed dismutation, thermodynamics and the so-called Haber-Weiss Reaction.
- Research Organization:
- Brookhaven National Lab., Upton, NY (USA)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC02-76CH00016
- OSTI ID:
- 6696963
- Report Number(s):
- BNL-28948
- Country of Publication:
- United States
- Language:
- English
Similar Records
Kinetics of the interaction of HO/sub 2/ and O/sub 2//sup -/ radicals with hydrogen peroxide. The Haber--Weiss reaction. [Gamma radiation]
Reaction between superoxide ion and the superoxide coordinated in a cobalt(III) complex
Photochemical generation of superoxide radicals in aqueous solutions
Journal Article
·
Tue Jan 02 23:00:00 EST 1979
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:6168796
Reaction between superoxide ion and the superoxide coordinated in a cobalt(III) complex
Journal Article
·
Wed Jun 18 00:00:00 EDT 1980
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:5101929
Photochemical generation of superoxide radicals in aqueous solutions
Journal Article
·
Wed Aug 30 00:00:00 EDT 1978
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:6509255
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400600 -- Radiation Chemistry
ABSORPTION SPECTRA
CHEMICAL PROPERTIES
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMISTRY
DECOMPOSITION
DOCUMENT TYPES
ELECTROLYSIS
LYSIS
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
RADIATION CHEMISTRY
RADIATION EFFECTS
RADICALS
RADIOLYSIS
REVIEWS
SPECTRA
SUPEROXIDE RADICALS
THERMODYNAMICS
YIELDS
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400600 -- Radiation Chemistry
ABSORPTION SPECTRA
CHEMICAL PROPERTIES
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMISTRY
DECOMPOSITION
DOCUMENT TYPES
ELECTROLYSIS
LYSIS
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
RADIATION CHEMISTRY
RADIATION EFFECTS
RADICALS
RADIOLYSIS
REVIEWS
SPECTRA
SUPEROXIDE RADICALS
THERMODYNAMICS
YIELDS