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U.S. Department of Energy
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Comparison of sampling methods for carbonaceous aerosols in ambient air. Final report, May 1987-April 1988

Technical Report ·
OSTI ID:6694020

Measurement methods for fine-particle carbon were compared under field-sampling conditions during the Carbonaceous Species Methods Comparison Study. Sampling methods included filtration, impaction and adsorption-corrected filtration. Systems were operated side-by-side for nine consecutive days in the Los Angeles Basin in August 1986. Analytical methods were compared separately. For organic carbon, ambient measurements showed greater variability than could be accounted for by differences in analytical measurements. Comparison of results from the different sampling systems and analysis of back-up filter data indicate adsorption artifacts on quartz-fiber filters can be significant. For the two impactor systems, the after-filters contained a large proportion of organic carbon (38% and 47%), but very little elemental carbon (5% and 12%). For systems employing tandem filters, the carbon found on the back-up filters was 14% to 53% of the aerosol carbon.

Research Organization:
California Univ., Los Angeles (USA). Dept. of Chemical Engineering
OSTI ID:
6694020
Report Number(s):
PB-88-240452/XAB
Country of Publication:
United States
Language:
English