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Rotational spectra of carbon 13 and vibrationally excited SiC

Journal Article · · Astrophysical Journal; (USA)
DOI:https://doi.org/10.1086/185684· OSTI ID:6690641
; ; ;  [1]
  1. Harvard Univ., Cambridge, MA (USA) Harvard-Smithsonian Center for Astrophysics, Cambridge, MA (USA)
The millimeter-wave rotational spectra of SiC-13 and vibrationally excited SiC in the X3Pi state have been measured between 149 and 291 GHz in a laboratory discharge through SiH4 and CO. Hyperfine splittings in the SiC-13 spectra are well resolved, allowing accurate determination of all four hyperfine constants. The fine-structure, rotational, centrifugal distortion, and lambda-doubling constants for SiC-13 and v = 1 SiC have been determined to sufficient accuracy that the entire rotational spectrum can be calculated into the far-IR. 15 refs.
OSTI ID:
6690641
Journal Information:
Astrophysical Journal; (USA), Journal Name: Astrophysical Journal; (USA) Vol. 352; ISSN ASJOA; ISSN 0004-637X
Country of Publication:
United States
Language:
English