Liquid-vapor and solid-liquid-vapor equilibrium in natural gas systems. Final report, January 1983-December 1985

Technical Report · Tue Oct 01 00:00:00 EDT 1985

OSTI ID:6688865

Sloan, E D; Kidnay, A J

The three-phase (SLV) equilibria for the methane + carbon dioxide system was measured at 206, 208, 210, 212, 214, and 216 K, and a complete isotherm was determined at 212 K. The ethane + carbon dioxide system was studied at 204, 206, 208, 209, 210, 212, 213, 214, 216 K and complete isotherms determined at 204, 207, 209, 210, 212, and 216 K. The propane + carbon dioxide system was studied at 208, 210, 212, 214, and 216 K with a complete isotherm measured at 216 K. Preliminary data on temperature, pressure, and mole fraction at the triple points are tabulated. Vapor liquid equilibria data are presented for the ethane + carbon dioxide system at 207, 210, 220, 223.15, 230, 250, 263.15, 270, 213, 230, 250, and 270 K. Binary interaction parameters were fit for the Soave-Redlich-Kwong equation of state. VLE measurements are presented for the nitrogen + ethane, and the nitrogen + carbon dioxide system at 220 K and 270 K. Measurements are also presented for the ternary system nitrogen + carbon dioxide + ethane at 220 K and at three pressures ranging from the pressure of 0.803 (the carbon dioxide + ethane azeotrope) to 9 MPa.

• Research Organization: Colorado School of Mines, Golden (USA)
• OSTI ID: 6688865
• Report Number(s): PB-87-153904/XAB
• Resource Relation: Other Information: See also PB--84-179191
• Country of Publication: United States
• Language: English

Related Subjects

03 NATURAL GAS
NATURAL GAS
PHASE STUDIES
CARBON DIOXIDE
EQUILIBRIUM
ETHANE
LOW TEMPERATURE
MATHEMATICAL MODELS
METHANE
ALKANES
CARBON COMPOUNDS
CARBON OXIDES
CHALCOGENIDES
ENERGY SOURCES
FLUIDS
FOSSIL FUELS
FUEL GAS
FUELS
GAS FUELS
GASES
HYDROCARBONS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
033000* - Natural Gas- Properties & Composition