Velocity dependence of the absolute cross sections for the chemi-ionization of Ar, Kr, and Xe on impact of 2/sup 1/S and 2/sup 3/S helium atoms
Journal Article
·
· J. Chem. Phys.; (United States)
OSTI ID:6687260
Measurements of the velocity dependence of the absolute cross sections for the chemi-ionization of Ar, Kr, and Xe on impact of thermal energy metastable helium atoms in the relative velocity range 1--3 km sec/sup -1/ have been made using a single velocity-selected beam, collision-chamber method. Separate measurements for both 2/sup 3/S and 2/sup 1/S helium atoms are obtained through the use of a He discharge lamp to quench the singlets from the beam. The metastable atom electron ejection efficiencies are separately measured in the same apparatus. The results are compared with the relative measurements of other workers. The constants are evaluated in a two-parameter exponential function representing the coupling width for decay of the discrete electronic state of the incoming channel into the continuum electronic state of the outgoing channel, which give the best fit to the experimental data for the He* (2/sup 3/S) --Ar and He* (2/sup 3/S) --Kr systems.
- Research Organization:
- Department of Chemistry, University of Florida, Gainesville, Florida 32611
- OSTI ID:
- 6687260
- Journal Information:
- J. Chem. Phys.; (United States), Journal Name: J. Chem. Phys.; (United States) Vol. 69:7; ISSN JCPSA
- Country of Publication:
- United States
- Language:
- English
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