Selectivity of the reactions of oxygenates on transition metal surfaces: Progress report, 15 December 1987--14 December 1988
Technical Report
·
OSTI ID:6682600
The goal of this research has been to understand, by means of surface science studies, the elementary processes involved in the synthesis of methanol and higher alcohols on transition metals, and the dependence of these processes upon the nature of the surface. To date we have completed TPD and HREELS studies of methanol, formaldehyde, formic acid, methyl formate, ethanol, acetaldehyde, acetic acid, 1-propanol, propanal, propionic acid, 2-propanol, acetone, allyl alcohol, acrolein, acrylic acid, and propylene on clean and oxygen-dosed Pd(111) surfaces. We have completed TPD, HREELS, and XPS studies of methanol, formaldehyde, and formic acid on clean and oxygen-dosed Rh(111) surfaces. 4 refs.
- Research Organization:
- Delaware Univ., Newark (USA)
- DOE Contract Number:
- FG02-84ER13290
- OSTI ID:
- 6682600
- Report Number(s):
- DOE/ER/13290-4; ON: DE89003691
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
090220* -- Alcohol Fuels-- Preparation-- (1976-1989)
10 SYNTHETIC FUELS
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
ADSORPTION
ALCOHOLS
ALDEHYDES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
DOCUMENT TYPES
ELEMENTS
ETHANOL
HYDROXY COMPOUNDS
KINETICS
METALS
METHANOL
ORGANIC COMPOUNDS
PALLADIUM
PLATINUM METALS
PROGRESS REPORT
PROPANOLS
REACTION INTERMEDIATES
REACTION KINETICS
RHODIUM
SORPTION
SPECIFICITY
SURFACE PROPERTIES
SYNTHESIS
TRANSITION ELEMENTS
10 SYNTHETIC FUELS
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
ADSORPTION
ALCOHOLS
ALDEHYDES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
DOCUMENT TYPES
ELEMENTS
ETHANOL
HYDROXY COMPOUNDS
KINETICS
METALS
METHANOL
ORGANIC COMPOUNDS
PALLADIUM
PLATINUM METALS
PROGRESS REPORT
PROPANOLS
REACTION INTERMEDIATES
REACTION KINETICS
RHODIUM
SORPTION
SPECIFICITY
SURFACE PROPERTIES
SYNTHESIS
TRANSITION ELEMENTS