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Interpretation of ES, CS, and IOS approximations within a translational--internal coupling scheme. III. Exact and CS molecule--molecule cross sections

Journal Article · · J. Chem. Phys.; (United States)
DOI:https://doi.org/10.1063/1.441264· OSTI ID:6676500
Properties of exact and centrifugal sudden translational--internal reduced S matrices are given for general molecule--molecule collisions. The structure of energy-dependent and kinetic cross sections appropriate for linearized kinetic theory are described, both exactly and within the CS approximation. Connection with analogous total-J coupling scheme expressions is made in the Appendix.
Research Organization:
Department of Chemistry, University of British Columbia, Vancouver, Canada V6T 1Y6
OSTI ID:
6676500
Journal Information:
J. Chem. Phys.; (United States), Journal Name: J. Chem. Phys.; (United States) Vol. 74:3; ISSN JCPSA
Country of Publication:
United States
Language:
English