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Electrochemical oxygen sensor for measurement of oxygen in liquid sodium

Journal Article · · Nucl. Technol.; (United States)
OSTI ID:6670297
The results obtained from approximately 4000 h of operation of an electrochemical oxygen meter developed at General Electric Company for measuring oxygen activities in liquid sodium are described. In the present design, a small ceramic cup (ThO/sub 2/ with 7 to 8 wt % Y/sub 2/O/sub 3/) has been brazed to a metal tube that is inserted into the liquid sodium via a standard sodium flange. The reference electrode used in the present design consists of In/In/sub 2/O/sub 3/. Several meters were tested in a flowing sodium system, where the oxygen concentrations were controlled by a cold trap. At 500/sup 0/C, the oxygen electromotive force (emf) output can be expressed as emf/sub (V)/ = 0.269 + (160/T) (+-0.003 V), where T is the cold-trap temperature in K. The temperature coefficient of the meters can be expressed as (dE/dT) = 0.51 +- (0.02) mV//sup 0/C.
Research Organization:
General Electric Co., San Jose, CA
OSTI ID:
6670297
Journal Information:
Nucl. Technol.; (United States), Journal Name: Nucl. Technol.; (United States) Vol. 39:2; ISSN NUTYB
Country of Publication:
United States
Language:
English

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