Infrared spectral studies of various metal polyacrylates

Journal Article · Fri Dec 01 04:00:00 EST 1989 · Journal of Solid State Chemistry; (USA)

DOI:https://doi.org/10.1016/0022-4596(89)90183-7· OSTI ID:6668210

McCluskey, P H; Snyder, R L; Condrate, Sr, R A ^[1]

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1. Alfred Univ., NY (USA)

A new process for the production of high surface area, high reactivity ceramic oxide powders involves the bonding of metal cations to polymeric polyacrylate chains. This process results in the formation of a gelatinous metal polyacrylate precipitate which can be easily removed from the mother liquor, and then calcined to form a high density ceramic oxide. Using FTIR spectroscopy, the nature of the structural arrangements has been studied for metal complexes in the yttrium, lanthanum, aluminum, cerium, copper, and iron polyacrylates. Interpretation of the infrared spectra indicates that two types of metal complex formation occur in these precipitates, involving bidentate or bridging interactions. The type that is observed for a particular metal ion is dependent on its metal ion size.

• OSTI ID: 6668210
• Journal Information: Journal of Solid State Chemistry; (USA), Journal Name: Journal of Solid State Chemistry; (USA) Vol. 83:2; ISSN JSSCB; ISSN 0022-4596
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
360603* -- Materials-- Properties
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400102 -- Chemical & Spectral Procedures
ALUMINIUM
CERIUM
COPPER
DATA
DATA ANALYSIS
ELEMENTS
ESTERS
EXPERIMENTAL DATA
INFORMATION
INFRARED SPECTRA
LANTHANUM
MEASURING INSTRUMENTS
MEASURING METHODS
METALS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC POLYMERS
POLYACRYLATES
POLYMERS
POLYVINYLS
PRODUCTION
RARE EARTHS
SPECTRA
TRANSITION ELEMENTS
YTTRIUM