Study of benzene release from Savannah River in-tank precipitation process slurry simulant

Technical Report · Sat Aug 01 04:00:00 EDT 1998

DOI:https://doi.org/10.2172/665985· OSTI ID:665985

Rappe, K G; Gauglitz, P A

At the Savannah River Site, the in-tank precipitation (ITP) process uses sodium tetraphenylborate (NaTPB) to precipitate radioactive cesium from alkaline wastes. During this process, potassium is also precipitated to form 4-wt% KTPB/CsTPB slurry. Residual NaTPB decomposes to form benzene, which is retained by the waste slurry. The retained benzene is also readily released from the waste during subsequent waste processing. While the release of benzene certainly poses flammability and toxicological safety concerns, the magnitude of the hazard depends on the rate of release. Currently, the mechanisms controlling the benzene release rates are not well understood, and predictive models for estimating benzene release rates are not available. The overall purpose of this study is to obtain quantitative measurements of benzene release rates from a series of ITP slurry simulants. This information will become a basis for developing a quantitative mechanistic model of benzene release rates. The transient benzene release rate was measured from the surface of various ITP slurry (solution) samples mixed with benzene. The benzene release rate was determined by continuously purging the headspace of a sealed sample vessel with an inert gas (nitrogen) and analyzing that purged headspace vapor for benzene every minute.

• Research Organization: Pacific Northwest National Lab., Richland, WA (United States)
• Sponsoring Organization: USDOE Office of Financial Management and Controller, Washington, DC (United States)
• DOE Contract Number: AC06-76RL01830
• OSTI ID: 665985
• Report Number(s): PNNL--12004; ON: DE98059361; BR: 83040300
• Country of Publication: United States
• Language: English

Related Subjects

05 NUCLEAR FUELS
BENZENE
CESIUM COMPOUNDS
DECOMPOSITION
DEGASSING
EXPERIMENTAL DATA
ORGANIC BORON COMPOUNDS
POTASSIUM COMPOUNDS
PRECIPITATION
RADIOACTIVE WASTE PROCESSING
SAVANNAH RIVER PLANT