Mechanism of oxidative addition of cyclopentadienyl-rhodium complexes to carbon-hydrogen and carbon-carbon bonds
Technical Report
·
OSTI ID:6653847
This document is divided into two parts: (1) Isomerization of the hydrido(alkyl)rhodium complexes formed on oxidative addition of rhodium to alkane C-H bonds. Evidence for the intermediacy of eta/sup 2/-C-H alkane complexes. (2) Thermal and photochemical C-C activation of cyclopropane and cyclobutane by (eta/sup 5/-C/sub 5/Me/sub 5/)(PMe/sub 3/)Rh). Mechanism of the rearrangement of cycloalkyl(hydrido)rhodium complexes to rhodacycloalkanes.
- Research Organization:
- Lawrence Berkeley Lab., CA (USA)
- DOE Contract Number:
- AC03-76SF00098
- OSTI ID:
- 6653847
- Report Number(s):
- LBL-22533; ON: DE87007163
- Country of Publication:
- United States
- Language:
- English
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Isomerization of the hydridoalkylrhodium complexes formed on oxidative addition of rhodium to alkane C-H bonds. Evidence for the intermediacy of eta/sup 2/-alkane complexes
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OSTI ID:7222764
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·
Tue Nov 11 23:00:00 EST 1986
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Fri Oct 31 23:00:00 EST 1986
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OSTI ID:5344975
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKANES
CHEMICAL REACTIONS
COMPLEXES
CYCLOALKANES
DECOMPOSITION
HYDROCARBONS
ISOMERIZATION
ORGANIC COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
PYROLYSIS
RHODIUM COMPLEXES
THERMOCHEMICAL PROCESSES
TRANSITION ELEMENT COMPLEXES
400201* -- Chemical & Physicochemical Properties
ALKANES
CHEMICAL REACTIONS
COMPLEXES
CYCLOALKANES
DECOMPOSITION
HYDROCARBONS
ISOMERIZATION
ORGANIC COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
PYROLYSIS
RHODIUM COMPLEXES
THERMOCHEMICAL PROCESSES
TRANSITION ELEMENT COMPLEXES