Electronic structures of perovskite oxides of transition metals of the type LaMO[sub 3] (M = Ti-Ni) as revealed by MSX[alpha] investigations
Journal Article
·
· Journal of Solid State Chemistry; (United States)
- Indian Institute of Science, Bangalore (India)
Systematic investigations of the electronic structures of MO[sup 9-][sub 6] (M = Ti-Ni) clusters, as in the LaMO[sub 3] type perovskite oxides, have been carried out by employing the multiple-scattering X[alpha] (MSX[alpha]) method. The crystal-field splitting of the metal d level is found to increase, while the oxygen-to-metal charge-transfer energy decreases across the transition metal series. Systematic trends are also seen in the mixing (covalency) between the metal d and the oxygen 2p orbitals in the series.
- OSTI ID:
- 6651846
- Journal Information:
- Journal of Solid State Chemistry; (United States), Journal Name: Journal of Solid State Chemistry; (United States) Vol. 110:2; ISSN 0022-4596; ISSN JSSCBI
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
CHALCOGENIDES
CHROMIUM COMPOUNDS
CHROMIUM OXIDES
COBALT COMPOUNDS
COBALT OXIDES
CRYSTAL FIELD
ELECTRONIC STRUCTURE
IRON COMPOUNDS
IRON OXIDES
LANTHANUM COMPOUNDS
LANTHANUM OXIDES
MANGANESE COMPOUNDS
MANGANESE OXIDES
MATHEMATICAL MODELS
NICKEL COMPOUNDS
NICKEL OXIDES
OXIDES
OXYGEN COMPOUNDS
RARE EARTH COMPOUNDS
TITANIUM COMPOUNDS
TITANIUM OXIDES
TRANSITION ELEMENT COMPOUNDS
VANADIUM COMPOUNDS
VANADIUM OXIDES
400201* -- Chemical & Physicochemical Properties
CHALCOGENIDES
CHROMIUM COMPOUNDS
CHROMIUM OXIDES
COBALT COMPOUNDS
COBALT OXIDES
CRYSTAL FIELD
ELECTRONIC STRUCTURE
IRON COMPOUNDS
IRON OXIDES
LANTHANUM COMPOUNDS
LANTHANUM OXIDES
MANGANESE COMPOUNDS
MANGANESE OXIDES
MATHEMATICAL MODELS
NICKEL COMPOUNDS
NICKEL OXIDES
OXIDES
OXYGEN COMPOUNDS
RARE EARTH COMPOUNDS
TITANIUM COMPOUNDS
TITANIUM OXIDES
TRANSITION ELEMENT COMPOUNDS
VANADIUM COMPOUNDS
VANADIUM OXIDES