Vacuum ultraviolet photochemistry of tetrahydrothiophene and sulfolane
The vacuum uv photolysis of tetrahydrothiophene (THT) involves the breaking of the S to ..cap alpha..-C bond. Besides ethylene, C/sub 3/H/sub 6/ and 1,3-butadiene are also formed. Photolyses of THT, tetrahydrofuran, and pyrrolidine are similar. The vacuum uv photolysis of tetramethylene sulfone (sulfolane) was also studied; products are SO/sub 2/, cyclobutane, 1-butene, and ethylene. No cis-2-butene was observed. (DLC)
- Research Organization:
- Worcester Polytechnic Inst., MA (USA). Dept. of Chemistry
- DOE Contract Number:
- AS02-76ER03569
- OSTI ID:
- 6651468
- Report Number(s):
- DOE/TIC-11399
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400500* -- Photochemistry
ALKENES
BUTADIENE
BUTENES
CHALCOGENIDES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CYCLOALKENES
DECOMPOSITION
DIENES
ELECTROMAGNETIC RADIATION
ETHYLENE
FAR ULTRAVIOLET RADIATION
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
KINETICS
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
POLYENES
RADIATIONS
REACTION KINETICS
SULFONES
SULFUR COMPOUNDS
SULFUR DIOXIDE
SULFUR OXIDES
ULTRAVIOLET RADIATION
400500* -- Photochemistry
ALKENES
BUTADIENE
BUTENES
CHALCOGENIDES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CYCLOALKENES
DECOMPOSITION
DIENES
ELECTROMAGNETIC RADIATION
ETHYLENE
FAR ULTRAVIOLET RADIATION
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
KINETICS
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
POLYENES
RADIATIONS
REACTION KINETICS
SULFONES
SULFUR COMPOUNDS
SULFUR DIOXIDE
SULFUR OXIDES
ULTRAVIOLET RADIATION