Magnetic correlations and quantum criticality in the insulating antiferromagnetic, insulating spin liquid, renormalized Fermi liquid, and metallic antiferromagnetic phases of the Mott system V{sub 2}O{sub 3}
- Physics Department, Brookhaven National Laboratory, Upton, New York 11973 (United States)
- Department of Physics and Astronomy, The Johns Hopkins University, Baltimore, Maryland 21218 (United States)
- NEC, 4 Independence Way, Princeton, New Jersey 08540 (United States)
- Department of Physics, University of California, Santa Cruz, California 95064 (United States)
- Solid State Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)
- James Franck Institute and Department of Physics, University of Chicago, Chicago, Illinois 60637 (United States)
- Department of Chemistry, Purdue University, West Lafayette, Indiana 47907 (United States)
- United States Army Research Laboratory, Adelphi, Maryland 20783 (United States)
Magnetic correlations in all four phases of pure and doped vanadium sesquioxide (V{sub 2}O{sub 3}) have been examined by magnetic thermal-neutron scattering. Specifically, we have studied the antiferromagnetic and paramagnetic phases of metallic V{sub 2{minus}y}O{sub 3}, the antiferromagnetic insulating and paramagnetic metallic phases of stoichiometric V{sub 2}O{sub 3}, and the antiferromagnetic and paramagnetic phases of insulating V{sub 1.944}Cr{sub 0.056}O{sub 3}. While the antiferromagnetic insulator can be accounted for by a localized Heisenberg spin model, the long-range order in the antiferromagnetic metal is an incommensurate spin-density wave, resulting from a Fermi surface nesting instability. Spin dynamics in the strongly correlated metal are dominated by spin fluctuations with a {open_quotes}single lobe{close_quotes} spectrum in the Stoner electron-hole continuum. Furthermore, our results in metallic V{sub 2}O{sub 3} represent an unprecedentedly complete characterization of the spin fluctuations near a metallic quantum critical point, and provide quantitative support for the self-consistent renormalization theory for itinerant antiferromagnets in the small moment limit. Dynamic magnetic correlations for {h_bar}{omega}{lt}k{sub B}T in the paramagnetic insulator carry substantial magnetic spectral weight. However, they are extremely short-ranged, extending only to the nearest neighbors. The phase transition to the antiferromagnetic insulator, from the paramagnetic metal and the paramagnetic insulator, introduces a sudden switching of magnetic correlations to a different spatial periodicity which indicates a sudden change in the underlying spin Hamiltonian. To describe this phase transition and also the unusual short-range order in the paramagnetic state, it seems necessary to take into account the orbital degrees of freedom associated with the degenerate {ital d} orbitals at the Fermi level in V{sub 2}O{sub 3}. {copyright} {ital 1998} {ital The American Physical Society}
- OSTI ID:
- 664710
- Journal Information:
- Physical Review, B: Condensed Matter, Vol. 58, Issue 19; Other Information: PBD: Nov 1998
- Country of Publication:
- United States
- Language:
- English
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