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Diffusion of helium isotopes in silicate glasses and minerals: Implications for petrogenesis and geochronology. Doctoral thesis

Technical Report ·
OSTI ID:6645898
Helium diffusivities in basaltic glasses at seafloor temperatures are about 10 to the -16th power sq cm/s suggesting only very low concentration samples will be compromised, and that U/He geochronology of submarine basalts may be feasible. Helium diffusivities at magmatic temperatures are 10 to the -11th power, to 10 to the -8th power sq cm/s in silicate minerals, too low to regionally homogenize helium in the mantle. Helium exchange rates limit xenolith origin depths and transport times. Faster He diffusion in pyroxene than olivine allows diffusive loss to be evaluated. Diffusivities of {sup 3}He produced by cosmic rays in surface rocks are less than 10 to the -20th power sq cm/s in olivine and quartz, suggesting exposure dating will not be limited by helium loss for ages up to 10,000,000 years. Similar conclusions were found for U/{sup 4}He dating of quartz. Part of the {sup 3}He/{sup 4}He variability (.01 to 9 R{sub a}) of island arc basalts from the western Pacific reflects post-eruptive helium addition. In unaltered samples, Kavachi submarine volcano has different {sup 3}He/{sup 4}He (6.9 + or - .2 R{sub a}) than the Woodlark Spreading Center (8-9 R{sub a}). A contribution from subducted Pacific lithosphere may explain this and 87 Sr/86 Sr variations.
Research Organization:
Woods Hole Oceanographic Institution, MA (USA)
OSTI ID:
6645898
Report Number(s):
PB-90-241738/XAB; WHOI--89-15
Country of Publication:
United States
Language:
English