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Hydrogen production from water by means of chemical cycles

Journal Article · · Ind. Eng. Chem., Process Des. Dev.; (United States)
DOI:https://doi.org/10.1021/i260057a018· OSTI ID:6643778
Its theoretical search for an optimum closed-cycle thermochemical process for the production of hydrogen has led the University of Pennsylvania to the tentative conclusion that, as previous research has shown for 2-step cycles, a workable 3-step cycle probably does not exist. Because economics impose a severe restriction on the allowable number of reaction steps, a thermochemical process involving four or more reactions cannot successfully compete with direct electrolysis for hydrogen production. The conclusion is based on a systematic thermodynamic analysis of the simplest and most promising 3-step processes that have been proposed and several 4-step cycles that can be considered as extensions of 3-step patterns.
OSTI ID:
6643778
Journal Information:
Ind. Eng. Chem., Process Des. Dev.; (United States), Journal Name: Ind. Eng. Chem., Process Des. Dev.; (United States) Vol. 15; ISSN IEPDA
Country of Publication:
United States
Language:
English