First-order study of property/composition relationships for Hanford Waste Vitrification Plant glasses

Technical Report · Fri Jan 01 04:00:00 EST 1993

DOI:https://doi.org/10.2172/6635894· OSTI ID:6635894

Piepel, G F; Hrma, P R; Bates, S O; Schweiger, M J; Smith, D E

A first-order composition variability study (CVS-I) was conducted for the Hanford Waste Vitrification Plant (HWVP) program to preliminarily characterize the effects on key glass properties of variations i selected glass (waste and frit) components. The components selected were Si0[sub 2],B[sub 2]O[sub 3],A1[sub 2]O[sub 3], Fe[sub 2]O[sub 3], ZrO[sub 2], Na[sub 2]O,Li[sub 2]O,CaO,MgO, and Others (all remaining waste components). A glass composition region was selected for study based on the expected range of glass compositions and the results of a previous series of scoping and solubility studies. Then, a 23-glass statistically-designed mixture experiment was conducted and data obtained for viscosity, electrical conductivity, glass transition temperature, thermal expansion, crystallinity, and durability [Materials Characterization Center (MCC-1) 28-day leach test and the 7-day Product Consistency Test (PCT)]. These data were modeled using first-order functions of composition, and the models were used to investigate the effects of the components on glass and melt properties. The CVS-I data and models will also be used to support the second-order composition variability study (CVS-II).

• Research Organization: Pacific Northwest Lab., Richland, WA (United States)
• Sponsoring Organization: DOE; USDOE, Washington, DC (United States)
• DOE Contract Number: AC06-76RL01830
• OSTI ID: 6635894
• Report Number(s): PNL-8502; ON: DE93007931
• Country of Publication: United States
• Language: English

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052002* -- Nuclear Fuels-- Waste Disposal & Storage
12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES
ALKALI METAL COMPOUNDS
ALKALINE EARTH METAL COMPOUNDS
ALUMINIUM COMPOUNDS
ALUMINIUM OXIDES
CALCIUM COMPOUNDS
CALCIUM OXIDES
CHALCOGENIDES
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DISSOLUTION
ELECTRIC CONDUCTIVITY
ELECTRICAL PROPERTIES
EXPANSION
GLASS
HANFORD RESERVATION
IRON COMPOUNDS
IRON OXIDES
LEACHING
MAGNESIUM COMPOUNDS
MAGNESIUM OXIDES
MATERIALS
NATIONAL ORGANIZATIONS
NUCLEAR FACILITIES
OXIDES
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
RADIOACTIVE MATERIALS
RADIOACTIVE WASTE FACILITIES
RADIOACTIVE WASTES
SEPARATION PROCESSES
SILICON COMPOUNDS
SILICON OXIDES
SODIUM COMPOUNDS
SODIUM OXIDES
THERMAL EXPANSION
THERMODYNAMIC PROPERTIES
TRANSITION ELEMENT COMPOUNDS
TRANSITION TEMPERATURE
US DOE
US ERDA
US ORGANIZATIONS
VARIATIONS
VISCOSITY
VITRIFICATION
WASTE FORMS
WASTES
ZIRCONIUM COMPOUNDS
ZIRCONIUM OXIDES