Evaluated kinetic and photochemical data for atmospheric chemistry
- Univ. of California, Riverside (United States)
- Univ. of Leeds (United Kingdom)
- Natural Environmental Research Council, Swindon (United Kingdom)
- National Inst. of Standards and Technology, Gaithersburg, MD (United States)
- Swiss Federal Inst. of Technology, Duebendorf (Switzerland)
- Univ. of Goettingen (Germany)
This paper updates and extends previous critical evaluations of the kinetics and photochemistry of gas phase chemical reactions of neutral species involved in atmosphere chemistry [J. Phys. Chem. Ref. Data 9, 295 (1980); 11, 327 (1982); 13, 1259 (1984); 18, 881 (1989)]. The work has been carried out by the authors under the auspices of the IUPAC Subcommittee on Gas Phase Kinetic Data Evaluation for Atmospheric Chemistry. Data sheets have been prepared for 489 thermal and photochemical reactions, containing summaries of the available experimental data with notes giving details of the experimental procedures. For each reaction, a preferred value of the rate coefficient at 298 K is given together with a temperature dependence where possible. The selection of the preferred value is discussed, and estimates of the accuracies of the rate coefficients and temperature coefficients have been made for each reaction. The data sheets are intended to provide the basic physical chemical data needed as input for calculations which model atmospheric chemistry. A table summarizing the preferred rate data is provided, together with an appendix listing the available data on enthalpies of formation of the reactant and product species.
- OSTI ID:
- 6616907
- Journal Information:
- Journal of Physical and Chemical Reference Data; (United States), Journal Name: Journal of Physical and Chemical Reference Data; (United States) Vol. 21:6; ISSN 0047-2689; ISSN JPCRBU
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
540120* -- Environment
Atmospheric-- Chemicals Monitoring & Transport-- (1990-)
AMBIENT TEMPERATURE
ATMOSPHERIC CHEMISTRY
BROMINE COMPLEXES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMISTRY
CHLORINE COMPLEXES
COMPILED DATA
COMPLEXES
DATA
ENERGY
EXPERIMENTAL DATA
FLUORINE COMPLEXES
FORMATION FREE ENTHALPY
FREE ENTHALPY
GREENHOUSE GASES
INFORMATION
IODINE COMPLEXES
KINETICS
MATTER
NITROGEN COMPLEXES
NUMERICAL DATA
ORGANIC COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHYSICAL PROPERTIES
REACTION KINETICS
SULFUR COMPLEXES
TEMPERATURE DEPENDENCE
THERMODYNAMIC PROPERTIES
VOLATILE MATTER