Structure of sodium 4-(1[prime]-heptylnonyl)benzenesulfonate adsorbed on alumina using [sup 2]H NMR
- Univ. of Missouri, Rolla (United States)
Deuterium NMR has been used to probe the molecular dynamics and structure of the surfactant sodium 4-(1[prime]-heptylnonyl)benzenesulfonate (SHBS) adsorbed from water solution onto alumina. In order to investigate the dynamics of the headgroup, the phenyl ring of the surfactant was specifically deuterated. Two different surface coverages were studied in the temperature range of [minus]30 to 80C. At the adsorption plateau, evidence for the presence of two distinct surfactant domains of approximately equal intensities, on the alumina surface, was found. One domain, the inner layer next to the solid surface, gave rise to a quadrupole splitting in the [sup 2]H NMR spectrum similar to that found for the surfactant in lamellar liquid crystals, whereas the second domain, the outer layer, gave rise to a broad unsplit resonance indicating a more isotropic environment. The chemical exchange between the two domains was found to be slow on the NMR timescale. At a lower coverage, a broad unsplit resonance appeared in the NMR spectrum, showing that the molecular motions are not sufficiently anisotropic to cause any observable quadrupole splittings. With increasing temperature, resonances for both samples were narrowed, and the quadrupole splitting was reduced, reflecting more rapid reorientations of the surfactant molecules.
- OSTI ID:
- 6606381
- Journal Information:
- Journal of Colloid and Interface Science; (United States), Journal Name: Journal of Colloid and Interface Science; (United States) Vol. 157:1; ISSN 0021-9797; ISSN JCISA5
- Country of Publication:
- United States
- Language:
- English
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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ADSORPTION
ALUMINIUM COMPOUNDS
ALUMINIUM OXIDES
CHALCOGENIDES
CHEMICAL REACTIONS
DEUTERATION
DEUTERIUM
ENERGY SOURCES
ENHANCED RECOVERY
FOSSIL FUELS
FUELS
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
ISOTOPES
LIGHT NUCLEI
MAGNETIC RESONANCE
MOLECULAR STRUCTURE
NUCLEAR MAGNETIC RESONANCE
NUCLEI
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PETROLEUM
RESONANCE
SORPTION
STABLE ISOTOPES
SULFONATES
SURFACTANTS
TEMPERATURE RANGE
TEMPERATURE RANGE 0065-0273 K
TEMPERATURE RANGE 0273-0400 K
WATER