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U.S. Department of Energy
Office of Scientific and Technical Information

Advanced thermochemical hydrogen cycles

Conference ·
OSTI ID:6603862

The overall objective of this program is to contribute to the development of practical thermochemical cycles for the production of hydrogen from water. Specific goals are: investigate and evaluate the technical and economic viability of thermochemical cycles as an advanced technology for producing hydrogen from water; investigate and evaluate the engineering principles involved in interfacing individual thermochemical cycles with the different thermal energy sources (high temperature fission, solar, and fusion); and conduct a continuing research and development effort to evaluate the use of solid sulfates, oxides and other compounds as potentially advanced cycles and as alternates to H/sub 2/SO/sub 4/ based cycles. Basic thermochemistry studies have been completed for two different steps in the decomposition of bismuth sulfate. Two different bismuth sulfate cycles have been defined for different sulfuric acid strengths. The eventual best cycle will depend on energy required to form sulfuric acid at different concentrations. A solids decomposition facility has been constructed and practical studies of solid decompositions are being conducted. The facility includes a rotary kiln system and a dual-particle fluidized bed system. Evaluation of different types of cycles for coupling with different heat sources is continuing.

Research Organization:
Los Alamos National Lab., NM (USA)
DOE Contract Number:
W-7405-ENG-36
OSTI ID:
6603862
Report Number(s):
LA-UR-81-1279; CONF-810535-1
Country of Publication:
United States
Language:
English