Reactivity of benzyl cation and of benzhydryl cation with alkenes in solution: initiation step in cationic polymerization
Journal Article
·
· Macromolecules; (United States)
The pulse radiolysis technique has been used to determine rate constants for the initiation step in cationic polymerization. The reactivity of the benzyl cation and of the benzhydryl cation toward some 13 alkenes in dichloroethane solution has been determined. The rate constants vary over four orders of magnitude with the molecular structure of the nucleophiles. The reactivity-molecular structue dependence is discussed.
- Research Organization:
- Ohio State Univ., Columbus
- OSTI ID:
- 6603414
- Journal Information:
- Macromolecules; (United States), Journal Name: Macromolecules; (United States) Vol. 13:1; ISSN MAMOB
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600* -- Radiation Chemistry
ALCOHOLS
ALKENES
ARYL RADICALS
BENZHYDROL
BENZYL RADICALS
CATIONS
CHARGED PARTICLES
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTIONS
CHEMISTRY
DATA
DECOMPOSITION
ELECTRONS
ELEMENTARY PARTICLES
EXPERIMENTAL DATA
FERMIONS
HYDROCARBONS
HYDROXY COMPOUNDS
INFORMATION
IONS
IRRADIATION
KINETICS
LEPTONS
NUMERICAL DATA
ORGANIC COMPOUNDS
POLYMERIZATION
PULSED IRRADIATION
RADIATION CHEMISTRY
RADIATION EFFECTS
RADICALS
RADIOLYSIS
REACTION KINETICS
400600* -- Radiation Chemistry
ALCOHOLS
ALKENES
ARYL RADICALS
BENZHYDROL
BENZYL RADICALS
CATIONS
CHARGED PARTICLES
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTIONS
CHEMISTRY
DATA
DECOMPOSITION
ELECTRONS
ELEMENTARY PARTICLES
EXPERIMENTAL DATA
FERMIONS
HYDROCARBONS
HYDROXY COMPOUNDS
INFORMATION
IONS
IRRADIATION
KINETICS
LEPTONS
NUMERICAL DATA
ORGANIC COMPOUNDS
POLYMERIZATION
PULSED IRRADIATION
RADIATION CHEMISTRY
RADIATION EFFECTS
RADICALS
RADIOLYSIS
REACTION KINETICS