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Title: Late Permian age of ammonium-bearing illite in Pennsylvania anthracites: Temporal constraints on coalification in the central Appalachians

Conference · · AAPG Bulletin
OSTI ID:6597358
 [1]
  1. Chevron Petroleum Technology Co., La Habra, CA (United States)

K/Ar dating of authigenic NH4-bearing illite in coal from the Anthracite region of eastern Pennsylvania yields apparent ages of 253-236 Ma ([+-]8 m.y.). The oldest K/Ar date of 253 Ma ([+-]8 m.y.) is a minimum age for the thermal event associated with anthracite formation and illite authigenesis. This date is probably within [approx]10 m.y. of the time at which coal-bearing rocks experienced peak temperatures, which suggests an age range of 265-255 Ma for this event. Age dates for authigenic NH[sub 4]-bearing illite reflect the approximate age of late-stage coalification (formation of anthracite-rank coal) because this mineral formed only during late-stage coalification (T=200-275[degrees]C) from a kaolinite (potassium-free) precursor, and the K/Ar data suggest that NH[sub 4] does not significantly influence the closure temperature of illite. K/Ar dates, in conjunction with paleomagnetic and vitrinite reflectance data, constrain the thermal pulse and deformation associated with the Alleghanian orogenic episode to a time period of 25-35 m.y., beginning in Early Permian time ([approx]285 Ma) after coal deposition, and concluding by Late Permian time ([approx]260-250 Ma). Syn- and post-folding secondary chemical remanent magnetizations constrain Alleghanian folding in the Central Appalachians to Late Permian time, which coincides with the postulated time range of 265-255 Ma for NH[sub 4]-bearing illite authigenesis and anthracite formation derived from the K/Ar data. The similar time range for anthracite formation and Alleghanian folding is consistent with vitrinite reflectance data that suggests anthracite formation was a syn-folding thermal event.

OSTI ID:
6597358
Report Number(s):
CONF-960527-; CODEN: AABUD2
Journal Information:
AAPG Bulletin, Vol. 5; Conference: Annual convention of the American Association of Petroleum Geologists, Inc. and the Society for Sedimentary Geology: global exploration and geotechnology, San Diego, CA (United States), 19-22 May 1996; ISSN 0149-1423
Country of Publication:
United States
Language:
English