An investigation of adducts of arsonic acids with amines by nuclear quadrupole resonance of /sup 75/As nuclei
Journal Article
·
· Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
OSTI ID:6593059
The /sup 75/As nuclear quadrupole resonance (NQR) spectra of the adducts of arsonic acids with amines of the general formula RAs(O)(OH)/sub 2/NR'/sub 3/ were studied. The adducts were synthesized by direct mixing of alcoholic solutions of arsonic acids with amines. A wide range of derivatives of arsonic acids with different pK/sub a/ values and aliphatic primary and secondary amines with different basicities were investigated by physicochemical methods. /sup 75/As NQR spectra of adducts of arsonic acids and amines in a crystalline phase were measured at 77/sup 0/K on an IS-3 NQR pulse spectrometer. Complete proton transfer from the molecule of the acid to the amine in adducts of arsonic acids with amines was postulated from this investigation.
- Research Organization:
- Academy of Sciences of the USSR, Kazan
- OSTI ID:
- 6593059
- Journal Information:
- Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 30:9; ISSN BACCA
- Country of Publication:
- United States
- Language:
- English
Similar Records
Effect of dietary arsonic acids on performance characteristics of swine waste anaerobic digesters
THE REACTION OF NIOBIUM(V) AND TANTALUM(V) HALIDES WITH ALIPHATIC AMINES
Nuclear magnetic and quadrupole resonance in metallic powders in the presence of strong quadrupole interaction: Rhenium metal
Journal Article
·
Mon Dec 31 23:00:00 EST 1979
· J. Anim. Sci.; (United States)
·
OSTI ID:5207067
THE REACTION OF NIOBIUM(V) AND TANTALUM(V) HALIDES WITH ALIPHATIC AMINES
Journal Article
·
Wed Jan 31 23:00:00 EST 1962
· J. Less-Common Metals
·
OSTI ID:4797173
Nuclear magnetic and quadrupole resonance in metallic powders in the presence of strong quadrupole interaction: Rhenium metal
Journal Article
·
Mon Feb 29 23:00:00 EST 1988
· Phys. Rev. B: Condens. Matter; (United States)
·
OSTI ID:5356722
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
AMINES
ARSENIC 75
ARSENIC COMPLEXES
ARSENIC COMPOUNDS
ARSENIC ISOTOPES
ARSONIC ACIDS
COMPLEXES
DATA
EXPERIMENTAL DATA
INFORMATION
INTERMEDIATE MASS NUCLEI
ISOMERIC TRANSITION ISOTOPES
ISOTOPES
NUCLEAR QUADRUPOLE RESONANCE
NUCLEI
NUMERICAL DATA
ODD-EVEN NUCLEI
ORGANIC ACIDS
ORGANIC ARSENIC COMPOUNDS
ORGANIC COMPOUNDS
RADIOISOTOPES
RESONANCE
SECONDS LIVING RADIOISOTOPES
STABLE ISOTOPES
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
AMINES
ARSENIC 75
ARSENIC COMPLEXES
ARSENIC COMPOUNDS
ARSENIC ISOTOPES
ARSONIC ACIDS
COMPLEXES
DATA
EXPERIMENTAL DATA
INFORMATION
INTERMEDIATE MASS NUCLEI
ISOMERIC TRANSITION ISOTOPES
ISOTOPES
NUCLEAR QUADRUPOLE RESONANCE
NUCLEI
NUMERICAL DATA
ODD-EVEN NUCLEI
ORGANIC ACIDS
ORGANIC ARSENIC COMPOUNDS
ORGANIC COMPOUNDS
RADIOISOTOPES
RESONANCE
SECONDS LIVING RADIOISOTOPES
STABLE ISOTOPES