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Finite-perturbation calculation of static quadrupole and mixed dipole-octupole polarizabilities for the ground states of the first-row atoms

Journal Article · · Phys. Rev., A; (United States)

Static quadrupole and mixed dipole-octupole polarizabilities are calculated from correlated wave functions for the ground states of the first-row atoms with estimated uncertainties of less than 3%. The following mean quadrupole polarizabilities are obtained for the atoms Li through Ne (in atomic units): 1428; 301.8; 145.7; 64.20; 30.72; 21.20; 12.69; 7.726. Correlation contributions are found to range from -12% (Be) to +20% (O).

Research Organization:
Fachbereich Chemie der Johann Wolfgang Goethe Universitaet Frankfurt a.M., Germany
OSTI ID:
6580796
Journal Information:
Phys. Rev., A; (United States), Journal Name: Phys. Rev., A; (United States) Vol. 18:5; ISSN PLRAA
Country of Publication:
United States
Language:
English