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Structure inheritance in the formation of mica from kaolin minerals under hydrothermal conditions

Journal Article · · Int. Geol. Rev.; (United States)
Using data from electron diffraction and X-ray diffraction studies of products of hydrothermal treatment of kaolinite-group minerals (polytypic modifications: kaolinite, dickite, nacrite, and halloysite) with salt solutions, the structural mechanism is identified for solid-phase transformation from structures with two-layered 1:1 sheets to mica structures with three-layered 2:1 sheets. A composite-sheet beidellite-like phase with polar distribution of tetrahedral charge was an important intermediate product. Structural inheritance in these transformations takes the form of preservation of the sequential orientation of the sheets and the degree of structural perfection.
OSTI ID:
6575876
Journal Information:
Int. Geol. Rev.; (United States), Journal Name: Int. Geol. Rev.; (United States) Vol. 24:9; ISSN IGREA
Country of Publication:
United States
Language:
English