Production of high octane gasoline
This patent describes a process for the production of a high octane gasoline, having an octane number not less than 87 (RON + 0), from a substantially dealkylated hydrocarbon feedstock comprising not less than 50 vol % aromatic content, an API gravity between 5 and 25, a nitrogen content between 50 and 650 ppm, and a hydrogen content between 8.9 and 12.5 wt %. It comprises: hydrotreating the substantially dealkylated feedstock in the presence of a hydrotreating catalyst comprising a hydrogenation/dehydrogenation metal on a support, under hydrotreating conditions, including a pressure not greater than 1200 psig, liquid hourly space velocity between 0.25 and 5, and temperature between 600{degrees} and 800{degrees} F.; contacting the hydrotreated substantially dealkylated feedstock with a catalyst comprising a silica matrix and a crystalline silicate zeolite having a Constraint Index less than 2. The contacting is conducted at hydrogen partial pressure between 600 and 1000 psi, temperatures not less than 700{degrees} F., LHSV between 0.25 and 2.5, and a conversion per pass to 385{degrees} F. end point gasoline no greater than 50% to form a product comprising a 385{degrees} F. end point gasoline and an unconverted, upgraded bottom fraction; and passing the unconverted, upgraded bottom fraction to a fluid catalytic cracking (FCC) unit for further processing.
- Assignee:
- Mobil Oil Corp., New York, NY (USA)
- Patent Number(s):
- US 4919789; A
- Application Number:
- PPN: US s 7-259211
- OSTI ID:
- 6571946
- Resource Relation:
- Patent File Date: 18 Oct 1988
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
GASOLINE
PRODUCTION
ANTIKNOCK RATINGS
API GRAVITY
CATALYSTS
CATALYTIC CRACKING
HYDROCRACKING
ZEOLITES
CHEMICAL REACTIONS
CRACKING
DECOMPOSITION
DENSITY
FUELS
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
LIQUID FUELS
MATERIALS
MINERALS
PETROLEUM PRODUCTS
PHYSICAL PROPERTIES
PYROLYSIS
THERMOCHEMICAL PROCESSES
020400* - Petroleum- Processing