Skip to main content
OSTI.GOVU.S. Department of Energy Office of Scientific and Technical Information
U.S. Department of Energy
Office of Scientific and Technical Information
 

Analysis of lignite liquefaction products processed with syngas and hydrogen sulfide. [Dibenzothiophene]

Technical Report ·
OSTI ID:6566705
; ;
A method for monitoring the presence of elemental and organic sulfur compounds in distillable low-rank coal liquefaction products utilizing column chromatography and dual detection (FID/FPD) capillary GC has been developed. The addition of H/sub 2/S to the continuous processing of Beulah, North Dakota lignite does not increase the amount or variety of sulfur-containing organic compounds in the recycle slurry ASTM-D1160 vacuum distillate products. It does, however, introduce sulfur and a variety of volatile sulfur-containing organics into the light oils condensed from the vapor phase in the reactor. The presence and variety of sulfur compounds after 12 to 14 reactor passes reflects the introduction of these components in the startup solvent. No increased mutagenicity was observed with the coal liquids processed with H/sub 2/S. The production of H-donors in the recycle slurry ASTM D-1160 distillates was enhanced by the presence of H/sub 2/S.
Research Organization:
Department of Energy, Grand Forks, ND (USA). Grand Forks Energy Technology Center
OSTI ID:
6566705
Report Number(s):
DOE/FC-1001; CONF-830303-1; ON: DE83001281
Country of Publication:
United States
Language:
English

Similar Records

Analysis of lignite liquefaction products processed with syngas and hydrogen sulfide
Conference · Fri Dec 31 23:00:00 EST 1982 · Prepr. Pap. - Am. Chem. Soc., Div. Fuel Chem.; (United States) · OSTI ID:5632516
Homogeneous catalysis of lignite liquefaction with hydrogen sulfide
Conference · Fri Dec 31 23:00:00 EST 1982 · OSTI ID:6504605
Process for coal liquefaction employing a superior coal liquefaction process solvent
Patent · Tue Sep 20 00:00:00 EDT 1983 · OSTI ID:5601733

Related Subjects

01 COAL, LIGNITE, AND PEAT
010405 -- Coal
Lignite
& Peat-- Hydrogenation & Liquefaction
010600* -- Coal
Lignite
& Peat-- Properties & Composition
BROWN COAL
CARBONACEOUS MATERIALS
CHALCOGENIDES
CHEMICAL ANALYSIS
CHROMATOGRAPHY
COAL
COAL LIQUEFACTION
COAL LIQUIDS
DATA
DISPERSIONS
ELEMENTS
ENERGY SOURCES
EXPERIMENTAL DATA
FLUIDS
FOSSIL FUELS
FUELS
GASES
HYDROGEN COMPOUNDS
HYDROGEN SULFIDES
INFORMATION
LIGNITE
LIQUEFACTION
LIQUID COLUMN CHROMATOGRAPHY
LIQUIDS
MASS SPECTROSCOPY
MATERIALS
MIXTURES
MONITORING
MUTAGEN SCREENING
NONMETALS
NUMERICAL DATA
OPTIMIZATION
ORGANIC COMPOUNDS
ORGANIC SOLVENTS
ORGANIC SULFUR COMPOUNDS
QUANTITATIVE CHEMICAL ANALYSIS
RECYCLING
SCREENING
SEPARATION PROCESSES
SLURRIES
SOLVENTS
SPECTROSCOPY
SULFIDES
SULFUR
SULFUR COMPOUNDS
SUSPENSIONS
SYNTHESIS GAS
THERMOCHEMICAL PROCESSES