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Distribution of iron during full loading of amberlite IRC-72 resin with uranium from nitrate solutions at 30/sup 0/C

Technical Report ·
DOI:https://doi.org/10.2172/6566314· OSTI ID:6566314
The integrity of resin-based fuel kernels used in the fabrication of fuel elements for a high-temperature gas-cooled reactor will depend, in part, on the concentration of iron incorporated in the resin particles during their loading with uranium. Consequently, assessment of chemical specifications for iron as an impurity in uranyl nitrate solution should be based on its distribution during the resin loading operation. For this purpose, the behavior of iron, as an impurity in uranyl nitrate solutions, was investigated under equilibrium conditions at 30/sup 0/C during full loading of Amberlite IRC-72 cation exchange reaction were derived from calculations based on complex coordination of ferric ion with the resin over the nitrate ion concentration range of approx. 0.5 to 2 N.
Research Organization:
Oak Ridge National Lab., TN (USA)
DOE Contract Number:
W-7405-ENG-36
OSTI ID:
6566314
Report Number(s):
ORNL/TM-6631
Country of Publication:
United States
Language:
English