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A new charge storage mechanism for electrochemical capacitors

Journal Article · · Journal of the Electrochemical Society; (United States)
DOI:https://doi.org/10.1149/1.2043984· OSTI ID:6559524
;  [1]
  1. Army Research Lab., Fort Monmouth, NJ (United States). Electronics and Power Sources Directorate

The hydrous form of ruthenium oxide (RuO[sub 2][center dot]xH[sub 2]O) has been demonstrated to be an excellent electrode material for electrochemical capacitors. This material, as prepared by a sol-gel process at low temperatures, is amorphous and electrically conductive. The specific capacitance is over 720 F/g. This value is at least two times higher than the highest value ever reported for such materials. The charge storage mechanism is believed to involve bulk electrochemical protonation of the oxide. This discovery opens a new avenue of research in the field of high energy density electrochemical capacitors.

OSTI ID:
6559524
Journal Information:
Journal of the Electrochemical Society; (United States), Journal Name: Journal of the Electrochemical Society; (United States) Vol. 142:1; ISSN 0013-4651; ISSN JESOAN
Country of Publication:
United States
Language:
English