Structure and characterization of (C/sub 5/H/sub 5/)/sub 2/Zr(H)BH/sub 3/CH/sub 3/
Journal Article
·
· Inorg. Chem.; (United States)
During unsuccessful attempts to synthesize CP/sup 2/Zr(BH/sub 3/CH/sub 3/)/sub 2/ where Cp = eta /sup 5/-C/sub 5/H/sub 5/, the monomeric hydride Cp/sub 2/Zr(H)BH/sub 3/ was isolated and characterized. Results of the /sup 1/H NMR and ir spectra of both Cp/sub 2/Zr(H)BH/sub 3/CH/sub 3/ and the deuterated compound Cp/sub 2/Zr(D)BD/sub 3/CH/sub 3/ were used to characterize the monomeric hydride. 20 references, 1 figure, 5 tables.
- Research Organization:
- Lawrence Berkeley Lab., CA
- OSTI ID:
- 6559276
- Journal Information:
- Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 26:8; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
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OSTI ID:269186
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKANES
AROMATICS
BORON COMPOUNDS
BORON HYDRIDES
DATA
DEUTERIUM
EXPERIMENTAL DATA
HYDRIDES
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
INFORMATION
ISOTOPES
LABELLED COMPOUNDS
LIGHT NUCLEI
NMR SPECTRA
NUCLEI
NUMERICAL DATA
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
POLYCYCLIC AROMATIC HYDROCARBONS
SPECTRA
STABLE ISOTOPES
TRANSITION ELEMENT COMPOUNDS
ZIRCONIUM COMPOUNDS
400201* -- Chemical & Physicochemical Properties
ALKANES
AROMATICS
BORON COMPOUNDS
BORON HYDRIDES
DATA
DEUTERIUM
EXPERIMENTAL DATA
HYDRIDES
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
INFORMATION
ISOTOPES
LABELLED COMPOUNDS
LIGHT NUCLEI
NMR SPECTRA
NUCLEI
NUMERICAL DATA
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
POLYCYCLIC AROMATIC HYDROCARBONS
SPECTRA
STABLE ISOTOPES
TRANSITION ELEMENT COMPOUNDS
ZIRCONIUM COMPOUNDS