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Title: Evaluation of synergy in tire rubber-coal coprocessing

Journal Article · · Industrial and Engineering Chemistry Research
DOI:https://doi.org/10.1021/ie980122o· OSTI ID:655532

The tire rubber-coal synergy is evaluated through the different roles that rubber can have in coprocessing systems. For that, two different experimental designs were used: a swept fixed-bed reactor and tubing bomb minireactors. In this way, coal was coprocessed with rubber liquids from rubber pyrolysis and rubber hydrogenation, in a hydrogen atmosphere at 400 C. Coal was mixed as well with rubber in different proportions and hydrogenated at 375, 400, and 425 C, and oils obtained were characterized by thin-layer chromatography to obtain hydrocarbon type composition. Rubber behavior was compared to each of the main components of tires, and all the results indicated that the slight synergy found can be due to the small free radicals from vulcanized rubber decomposition, which are able to stabilize coal radicals to light products.

OSTI ID:
655532
Journal Information:
Industrial and Engineering Chemistry Research, Vol. 37, Issue 9; Other Information: PBD: Sep 1998
Country of Publication:
United States
Language:
English