Ionic conductivities and glass transition temperatures of Na/sub 2/O-ZrO/sub 2/-Al/sub 2/O/sub 3/-SiO/sub 2/ glasses

Journal Article · Wed Oct 01 00:00:00 EDT 1986 · J. Electrochem. Soc.; (United States)

DOI:https://doi.org/10.1149/1.2108328· OSTI ID:6553269

Kucera, G H; Bloom, I; Roche, M F

This paper extends the study of the thermal and electrical properties of glasses in the Na/sub 2/O-Al/sub 2/O/sub 3/-SiO/sub 2/ and Na/sub 2/O-ZrO/sub 2/-SiO/sub 2/ systems and provides data on new glasses in the Na/sub 2/O-Al/sub 2/O/sub 3/-ZrO/sub 2/-SiO/sub 2/ system. The data show that these sodium-ion-conducting glasses have desirable characteristics for use in sodium/sulfur cells, i.e., a rho of 100-200 ..cap omega..-cm at 300/sup 0/C and at T/sub g/ of 500/sup 0/-600/sup 0/C.

• Research Organization: Chemical Technology Div., Argonne National Lab., Argonne, IL 60439
• DOE Contract Number: W-31109-ENG-38
• OSTI ID: 6553269
• Journal Information: J. Electrochem. Soc.; (United States), Journal Name: J. Electrochem. Soc.; (United States) Vol. 133:10; ISSN JESOA
• Country of Publication: United States
• Language: English

Related Subjects

25 ENERGY STORAGE
250903* -- Energy Storage-- Batteries-- Materials
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& Auxiliaries
36 MATERIALS SCIENCE
360204 -- Ceramics
Cermets
& Refractories-- Physical Properties
ALKALI METAL COMPOUNDS
ALUMINIUM COMPOUNDS
ALUMINIUM OXIDES
CHALCOGENIDES
ELECTRIC BATTERIES
ELECTRIC CONDUCTIVITY
ELECTRICAL PROPERTIES
ELECTROCHEMICAL CELLS
GLASS
HIGH TEMPERATURE
IONIC CONDUCTIVITY
MATERIALS TESTING
METAL-NONMETAL BATTERIES
OXIDES
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
SILICON COMPOUNDS
SILICON OXIDES
SODIUM COMPOUNDS
SODIUM OXIDES
SODIUM-SULFUR BATTERIES
TESTING
THERMODYNAMIC PROPERTIES
TRANSITION ELEMENT COMPOUNDS
TRANSITION TEMPERATURE
ZIRCONIUM COMPOUNDS
ZIRCONIUM OXIDES