Structural studies of precursor and partially oxidized conducting complexes. XVII. Synthesis and electrical properties of the first homologous series of 1-dimensional (Pt--Pt) metals containing the FHF/sup -/ and F/sup -/ anions
Journal Article
·
· J. Am. Chem. Soc.; (United States)
The preparation, crystal lattice type, and electrical conductivity of a number of partially oxidized tetracyanoplatinate (POTCP) complexes containing the (FHF)/sup -/ ion are reported. All compounds were prepared in aqueous solutions by oxidation of the Pt(II) salt, M/sub 2/(Pt(CN)/sub 4/), either with hydrogen peroxide or electrolytically in the presence of MF and HF (M = potassium, rubidium, or cesium). Single-crystal electrical conductivities (4 probe) show that those complexes with the shorter Pt--Pt separations and correspondingly higher degree of partial oxidation also appear to have higher conductivities. The Pt--Pt bond lengths vary from 2.798 in the rubidium complex to 2.923 in the potassium complex.
- Research Organization:
- Argonne National Lab., IL
- OSTI ID:
- 6547872
- Journal Information:
- J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 100:17; ISSN JACSA
- Country of Publication:
- United States
- Language:
- English
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Journal Article
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Mon Aug 01 00:00:00 EDT 1977
· Inorg. Chem.; (United States)
·
OSTI ID:7078220
Structural studies of precursor and partially oxidized conducting complexes. 20. A reduction in platinum-chain dimerization in rubidium tetracyanoplatinate chloride (2:1:0. 3) trihydrate, Rb/sub 2/(Pt(CN)/sub 4/)Cl/sub 0/ /sub 3/. 3. 0 H/sub 2/O, at 110 K as revealed by a neutron diffraction study
Journal Article
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Sun Jul 01 00:00:00 EDT 1979
· Inorg. Chem.; (United States)
·
OSTI ID:6063598
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKALI METAL COMPLEXES
AQUEOUS SOLUTIONS
BOND LENGTHS
CESIUM COMPLEXES
CHEMICAL REACTIONS
COMPLEXES
DISPERSIONS
ELECTRIC CONDUCTIVITY
ELECTRICAL PROPERTIES
HYDRATES
MIXTURES
OXIDATION
PHYSICAL PROPERTIES
POTASSIUM COMPLEXES
RUBIDIUM COMPLEXES
SOLUTIONS
SPACE GROUPS
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
TEMPERATURE DEPENDENCE
400201* -- Chemical & Physicochemical Properties
ALKALI METAL COMPLEXES
AQUEOUS SOLUTIONS
BOND LENGTHS
CESIUM COMPLEXES
CHEMICAL REACTIONS
COMPLEXES
DISPERSIONS
ELECTRIC CONDUCTIVITY
ELECTRICAL PROPERTIES
HYDRATES
MIXTURES
OXIDATION
PHYSICAL PROPERTIES
POTASSIUM COMPLEXES
RUBIDIUM COMPLEXES
SOLUTIONS
SPACE GROUPS
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
TEMPERATURE DEPENDENCE