Topotactic redox reactions of the channel type chalcogenides Mo/sub 3/S/sub 4/ and Mo/sub 3/Se/sub 4/. [Formation of ternary phases A/sub x/Mo/sub 3/X/sub 4/, where A is transition or main group element]
Journal Article
·
· Mater. Res. Bull.; (United States)
OSTI ID:6547705
- Univ. of Muenster, Ger.
Mo/sub 3/S/sub 4/ and Mo/sub 3/Se/sub 4/ were found to undergo topotactic electron-ion exchange reactions at ambient temperatures in aqueous and nonaqueous electrolytes containing transition or main group cations. The products of cathodic reduction are ternary phases A/sub x/Mo/sub 3/X/sub 4/. Mobilities of the exchangeable cations are rather high inside the solid and are responsible for high reaction rates. Cathodic reduction of Mo/sub 3/S/sub 4/ and Mo/sub 3/Se/sub 4/ represents a suitable method for the preparation of both stoichiometric and nonstoichiometric ternary phases which are of interest with respect to the superconducting properties of these chalcogenides.
- OSTI ID:
- 6547705
- Journal Information:
- Mater. Res. Bull.; (United States), Journal Name: Mater. Res. Bull.; (United States) Vol. 12:8; ISSN MRBUA
- Country of Publication:
- United States
- Language:
- English
Similar Records
A facile synthesis of pseudo one-monodimensional ternary molybdenum chalcogenides M/sub 2/Mo/sub 6/X/sub 6/ (X = Se,Te; M = Li,Na. Cs)
New A/sub x/Nb/sub 6/Se/sub 8/ (A = Na,K,Rb,Cu,Ag,Zn,Cd,Pb) phases with the Nb/sub 3/Te/sub 4/ structure
Band Gap Engineering and Metastable Phase Discovery in Cu2BaSnS4–xSex Nanocrystals via Topotactic Anion Exchange
Journal Article
·
Sun Jul 01 00:00:00 EDT 1984
· Mater. Res. Bull.; (United States)
·
OSTI ID:5049023
New A/sub x/Nb/sub 6/Se/sub 8/ (A = Na,K,Rb,Cu,Ag,Zn,Cd,Pb) phases with the Nb/sub 3/Te/sub 4/ structure
Journal Article
·
Tue Mar 31 23:00:00 EST 1987
· Mater. Res. Bull.; (United States)
·
OSTI ID:6359839
Band Gap Engineering and Metastable Phase Discovery in Cu2BaSnS4–xSex Nanocrystals via Topotactic Anion Exchange
Journal Article
·
Mon Jun 09 00:00:00 EDT 2025
· Journal of the American Chemical Society
·
OSTI ID:2570063
Related Subjects
36 MATERIALS SCIENCE
360601 -- Other Materials-- Preparation & Manufacture
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
CATIONS
CHALCOGENIDES
CHARGE EXCHANGE
CHARGED PARTICLES
CHEMICAL PREPARATION
CHEMICAL REACTIONS
COPPER COMPOUNDS
COPPER SELENIDES
COPPER SULFIDES
ELECTRIC CONDUCTIVITY
ELECTRICAL PROPERTIES
ELECTROLYTES
ELECTRONS
ELEMENTARY PARTICLES
FERMIONS
IONS
IRON COMPOUNDS
IRON SELENIDES
IRON SULFIDES
LEPTONS
MOBILITY
MOLYBDENUM COMPOUNDS
MOLYBDENUM SELENIDES
MOLYBDENUM SULFIDES
NICKEL COMPOUNDS
NICKEL SELENIDES
NICKEL SULFIDES
PHYSICAL PROPERTIES
REDOX REACTIONS
SELENIDES
SELENIUM COMPOUNDS
SULFIDES
SULFUR COMPOUNDS
SUPERCONDUCTIVITY
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
360601 -- Other Materials-- Preparation & Manufacture
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
CATIONS
CHALCOGENIDES
CHARGE EXCHANGE
CHARGED PARTICLES
CHEMICAL PREPARATION
CHEMICAL REACTIONS
COPPER COMPOUNDS
COPPER SELENIDES
COPPER SULFIDES
ELECTRIC CONDUCTIVITY
ELECTRICAL PROPERTIES
ELECTROLYTES
ELECTRONS
ELEMENTARY PARTICLES
FERMIONS
IONS
IRON COMPOUNDS
IRON SELENIDES
IRON SULFIDES
LEPTONS
MOBILITY
MOLYBDENUM COMPOUNDS
MOLYBDENUM SELENIDES
MOLYBDENUM SULFIDES
NICKEL COMPOUNDS
NICKEL SELENIDES
NICKEL SULFIDES
PHYSICAL PROPERTIES
REDOX REACTIONS
SELENIDES
SELENIUM COMPOUNDS
SULFIDES
SULFUR COMPOUNDS
SUPERCONDUCTIVITY
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS