Electron nuclear double resonance study of Bis(acetylacetonato)oxovanadium(IV) and some of its adducts in frozen solution

Journal Article · Thu Jul 08 04:00:00 EDT 1982 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j100211a037· OSTI ID:6538450

Kirste, B; van Willigen, H

The bis(acetylacetonato)oxovanadium(IV) (VO(acac)/sub 2/) complex and its adducts with methanol and substituted pyridines in frozen solution have been studied by ENDOR (electron nuclear double resonance). The measured ligand hyperfine splitting and quadrupole coupling components give a detailed insight into the structure of the complexes. The experimental data allow us to discriminate between possible binding sites of the sixth ligand. Whereas methanol evidently binds to the vacant axial position, either cis or trans isomers may be formed with substituted pyridines. Our results are compared with those of previous infrared studies. 5 figures, 3 tables.

• Research Organization: Univ. of Massachusetts, Boston
• DOE Contract Number: AC02-81ER10911
• OSTI ID: 6538450
• Journal Information: J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 86:14; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ADDUCTS
ALCOHOLS
AROMATICS
AZINES
CHALCOGENIDES
CHELATES
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORINATED ALIPHATIC HYDROCARBONS
CHLOROFORM
COMMUNICATIONS
COMPLEXES
COMPUTERIZED CONTROL SYSTEMS
CONFIGURATION INTERACTION
CONTROL SYSTEMS
DATA
DATA PROCESSING
DATA TRANSMISSION
DOUBLE RESONANCE METHODS
ELECTRON SPIN RESONANCE
ENDOR
EXPERIMENTAL DATA
HALOGENATED ALIPHATIC HYDROCARBONS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
HYDROXY COMPOUNDS
HYPERFINE STRUCTURE
INFORMATION
KETONES
LIGANDS
LOW TEMPERATURE
MAGNETIC RESONANCE
METHANOL
NUMERICAL DATA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SOLVENTS
OXIDES
OXYGEN COMPOUNDS
PROCESSING
PYRIDINES
RESONANCE
SOLVENTS
STRUCTURAL CHEMICAL ANALYSIS
TEMPERATURE DEPENDENCE
TOLUENE
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
VANADIUM COMPLEXES
VANADIUM COMPOUNDS
VANADIUM OXIDES
YIELDS