Biomimetic catalyst of light hydrocarbons to their associated alcohols
Technical Report
·
OSTI ID:6534268
- Lawrence Berkeley Lab., CA (USA)
Metal complexes that mimic the active site of monooxygenase enzymes and convert carbon-hydrogen bonds to carbon-hydroxyl in the presence of a monooxygen transfer reagent are called biomimetic catalysts. Studies concerning the activation of methane, ethane, propane, and cyclohexane to their respective alcohols with biomimetic catalysts that encompass manganese and iron supramolecule porphyrins; manganese and iron non-porphyrin di, tri, and tetranuclear clusters; and manganese mononuclear substituted Keggin ions in the presence of iodosylbenzene, t-butyl hydroperoxide, hydrogen peroxide, and O{sub 2} gas as monooxygen transfer reagents will be discussed. 12 refs., 2 figs., 5 tabs.
- Research Organization:
- Electric Power Research Inst., Palo Alto, CA (USA); Lawrence Berkeley Lab., CA (USA)
- Sponsoring Organization:
- EPRI
- OSTI ID:
- 6534268
- Report Number(s):
- EPRI-ER-6663
- Country of Publication:
- United States
- Language:
- English
Similar Records
Biomimetic catalysis: Hydroxylation of C/sub 2/, C/sub 3/, and cycloC/sub 6/ hydrocarbons by managanese porphyrin and non-porphyrin catalysts in the presence of monooxygen transfer reagents
Biomimetic oxidation studies. 11: Alkane functionalization in aqueous solution utilizing in situ formed [Fe{sub 2}O({eta}{sup 1}-H{sub 2}O)({eta}{sup 1}-OAc)(TPA){sub 2}]{sup 3+}, as an MMO model precatalyst, embedded in surface-derivatized silica and contained in micelles
Novel catalysts for methane activation
Conference
·
Mon Aug 01 00:00:00 EDT 1988
·
OSTI ID:6206080
Biomimetic oxidation studies. 11: Alkane functionalization in aqueous solution utilizing in situ formed [Fe{sub 2}O({eta}{sup 1}-H{sub 2}O)({eta}{sup 1}-OAc)(TPA){sub 2}]{sup 3+}, as an MMO model precatalyst, embedded in surface-derivatized silica and contained in micelles
Journal Article
·
Mon Jul 26 00:00:00 EDT 1999
· Inorganic Chemistry
·
OSTI ID:677950
Novel catalysts for methane activation
Conference
·
Wed Dec 31 23:00:00 EST 1986
·
OSTI ID:5566228
Related Subjects
10 SYNTHETIC FUELS
100200* -- Synthetic Fuels-- Production-- (1990-)
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
ALCOHOL FUELS
ALCOHOLS
ALKANES
BIOMIMETIC PROCESSES
CARBOXYLIC ACIDS
CATALYSIS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL BONDS
CHEMICAL REACTION KINETICS
CLEAVAGE
CONVERSION
CRYSTAL STRUCTURE
CYCLOALKANES
CYCLOHEXANE
ELEMENTS
ENERGY SOURCES
ETHANE
FLUIDS
FOSSIL FUELS
FUEL GAS
FUELS
GAS FUELS
GASES
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
HYDROXY COMPOUNDS
IRON COMPOUNDS
IRON OXIDES
KINETICS
MANGANESE
METALS
METHANE
METHANOL
MICROSTRUCTURE
NATURAL GAS
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PORPHYRINS
PRODUCTION
PROPANE
REACTION KINETICS
SYNTHETIC FUELS
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
100200* -- Synthetic Fuels-- Production-- (1990-)
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
ALCOHOL FUELS
ALCOHOLS
ALKANES
BIOMIMETIC PROCESSES
CARBOXYLIC ACIDS
CATALYSIS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL BONDS
CHEMICAL REACTION KINETICS
CLEAVAGE
CONVERSION
CRYSTAL STRUCTURE
CYCLOALKANES
CYCLOHEXANE
ELEMENTS
ENERGY SOURCES
ETHANE
FLUIDS
FOSSIL FUELS
FUEL GAS
FUELS
GAS FUELS
GASES
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
HYDROXY COMPOUNDS
IRON COMPOUNDS
IRON OXIDES
KINETICS
MANGANESE
METALS
METHANE
METHANOL
MICROSTRUCTURE
NATURAL GAS
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PORPHYRINS
PRODUCTION
PROPANE
REACTION KINETICS
SYNTHETIC FUELS
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS