Synthetic and catalytic studies directed toward homogeneously catalyzed selective oxidation. Final report
Technical Report
·
OSTI ID:6532950
This final report briefly summarizes achievements made on catalyzed oxidation of carbon monoxide and ketones by transition metal carbonyl complexes. Only Rh(CO)/sub 16/ catalyzed the oxidation of CO under ambient conditions. A necessary condition for oxidation to occur is the facile substitution of PPh/sub 3/ into the coordination sphere of the metal catalytic oxidation of aliphatic ketones by rhodium and rhenium carbonyl complexes lead to the formation of carboxylic acids. Mechanistically the reaction proceeds via hydroperoxide and peracid intermediates. The catalysts accelerate the decomposition of hydroperoxide and peracid to carboxylic acids.
- Research Organization:
- Washington State Univ., Pullman (USA)
- DOE Contract Number:
- AT06-76ER71015
- OSTI ID:
- 6532950
- Report Number(s):
- DOE/ER/71015-T1; ON: DE83008383
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
AMBIENT TEMPERATURE
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CARBONYLS
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COMPLEXES
KETONES
KINETICS
ORGANIC COMPOUNDS
OXIDATION
OXIDES
OXYGEN COMPOUNDS
PHOSPHORUS COMPOUNDS
REACTION KINETICS
RESEARCH PROGRAMS
RHENIUM COMPLEXES
RHODIUM COMPLEXES
TRANSITION ELEMENT COMPLEXES
400201* -- Chemical & Physicochemical Properties
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
AMBIENT TEMPERATURE
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CARBONYLS
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COMPLEXES
KETONES
KINETICS
ORGANIC COMPOUNDS
OXIDATION
OXIDES
OXYGEN COMPOUNDS
PHOSPHORUS COMPOUNDS
REACTION KINETICS
RESEARCH PROGRAMS
RHENIUM COMPLEXES
RHODIUM COMPLEXES
TRANSITION ELEMENT COMPLEXES