Process for improving octane by the conversion of fused multi-ring aromatics and hydroaromatics to lower molecular weight compounds
A process is described for the conversion of a feed comprised of hydrocarbon compounds selected from the group consisting of a fused two-ring aromatic hydrocarbon compound, a fused two-ring hydroaromatic hydrocarbon compound, and a admixture of fused two-ring aromatic hydrocarbons and fused two-ring hydroaromatic hydrocarbons, having an initial boiling point of at least about 177/sup 0/C (350/sup 0/F) to lower boiling, higher octane hydrocarbons which comprises: contacting the feed, in the presence of hydrogen,over a catalyst comprised of elemental iron and one or more alkali or alkaline-earth metals components at a temperature ranging from about 225/sup 0/C to about 430/sup 0/C and hydrogen partial pressure ranging from about 0 psig to about 1000 psig sufficient to selectively hydrogenate and hydrocrack the fused two-ring aromatic hydrocarbon compound.
- Assignee:
- Exxon Research and Engineering Co., Florham Park, NJ
- Patent Number(s):
- US 4664777
- OSTI ID:
- 6532766
- Resource Relation:
- Patent File Date: Filed date 31 Jul 1985
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
PETROLEUM
ANTIKNOCK RATINGS
HYDROCRACKING
ALKALI METAL COMPOUNDS
ALKALINE EARTH METAL COMPOUNDS
AROMATICS
BOILING POINTS
CATALYSTS
HIGH TEMPERATURE
HYDROCARBONS
HYDROGEN
IRON
MIXTURES
MOLECULAR WEIGHT
OCTANE
PARTIAL PRESSURE
ALKANES
CHEMICAL REACTIONS
CRACKING
DECOMPOSITION
DISPERSIONS
ELEMENTS
ENERGY SOURCES
FOSSIL FUELS
FUELS
METALS
NONMETALS
ORGANIC COMPOUNDS
PHYSICAL PROPERTIES
PYROLYSIS
THERMOCHEMICAL PROCESSES
THERMODYNAMIC PROPERTIES
TRANSITION ELEMENTS
TRANSITION TEMPERATURE
020400* - Petroleum- Processing
023000 - Petroleum- Properties & Composition