Sorption of polynuclear aromatic hydrocarbons by sediments and soils
The sorption of pyrene, 3-methylcholanthrene, 7,12-dimethylbenz(a)anthracene, and dibenzanthracene on 14 soil and sediment samples exhibiting a wide range of physicochemical properties was studied. The equilibrium Freundlich constants and linear partition coefficients for each compound were highly correlated with the organic carbon content of the soils/sediments tested. No other significant correlations with soil/sediment properties were observed. The sorption constants when normalized to organic carbon content of the substrate predicted the octanol-water partition coefficients for the compounds tested. A highly significant negative correlation was observed between log substrate and log water solubility for these compounds. Experimental values of the water solubility and octanol-water partition coefficients for the four compounds are reported.
- Research Organization:
- Univ of Maryl
- OSTI ID:
- 6531776
- Journal Information:
- Environ. Sci. Technol.; (United States), Journal Name: Environ. Sci. Technol.; (United States) Vol. 14:12; ISSN ESTHA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
510200* -- Environment
Terrestrial-- Chemicals Monitoring & Transport-- (-1989)
54 ENVIRONMENTAL SCIENCES
ADSORPTION
AROMATICS
BENZANTHRACENE
CONDENSED AROMATICS
CORRELATIONS
HYDROCARBONS
ORGANIC COMPOUNDS
ORGANIC MATTER
POLYCYCLIC AROMATIC HYDROCARBONS
PYRENE
SEDIMENTS
SOILS
SORPTION