Analysis of residual organic materials in aqueous radioactive streams from the Purex process

Technical Report · Fri May 01 04:00:00 EDT 1987

DOI:https://doi.org/10.2172/6531172· OSTI ID:6531172

Shook, Jr, H E

New solid phase extraction methods have been developed to allow determination of residual normal paraffin hydrocarbon (NPH) and tri-n-butyl phosphate (TBP) in aqueous radioactive streams from the Purex process. The techniques concentrate organic materials and separate them from radioactive species for analysis by gas chromatography. TBP and NPH have good radiolytic and chemical stability and have low aqueous solubility. However, they can contaminate aqueous streams and cause processing difficulties. Knowledge of the concentration of organic materials in aqueous waste is useful in assessing impact on pollution control equipment. The storage quality of diluent-washed aqueous plutonium product solution can be determined by a gas chromatographic analysis for residual TBP. 4 refs., 1 fig., 7 tabs.

• Research Organization: Savannah River Lab., Aiken, SC (USA)
• DOE Contract Number: AC09-76SR00001
• OSTI ID: 6531172
• Report Number(s): DP-1744; ON: DE87010562
• Country of Publication: United States
• Language: English

Related Subjects

050800* -- Nuclear Fuels-- Spent Fuels Reprocessing
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS
ALKANES
AQUEOUS SOLUTIONS
BUTYL PHOSPHATES
CHROMATOGRAPHY
DISPERSIONS
ESTERS
EXTRACTION
GAS CHROMATOGRAPHY
HYDROCARBONS
MATERIALS
MIXTURES
ORGANIC COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
PHOSPHORIC ACID ESTERS
PUREX PROCESS
RADIOACTIVE EFFLUENTS
RADIOACTIVE MATERIALS
RADIOACTIVE WASTES
REPROCESSING
SAMPLING
SEPARATION PROCESSES
SOLUTIONS
TBP
WASTES