Deuteration of piperylene on zeolite NaY

Journal Article · Tue Apr 20 04:00:00 EST 1982 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

OSTI ID:6524545

Kharlamov, V V; Kadentsev, V I; Kharatishvili, N G; Minachev, Kh M

In order to further refine the mechanism of hydrogenation reaction on zeolites, the deuteration of piperylene on NaY was studied. The kinetic isotope effect in the hydrogenation of piperylene on zeolite NaY indicates that hydrogen takes part in the limiting step of the process and the 1-pentene and 2-pentene formed in the deuteration of piperylene have a wide isotope distribution, with a maximum amount of the d/sub 2/ isotope, and an average number of deuterium atoms in the molecules equal to 2.25-2.36.

• Research Organization: Academy of Sciences of USSR, Moscow
• OSTI ID: 6524545
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 30:10; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400302* -- Organic Chemistry-- Isotope Effects-- (-1987)
ALKENES
CATALYTIC EFFECTS
CHEMICAL REACTIONS
COMPLEXES
DEUTERATION
DEUTERIUM
HYDROCARBONS
HYDROGEN ISOTOPES
HYDROGENATION
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
ISOTOPE APPLICATIONS
ISOTOPE EFFECTS
ISOTOPES
LIGHT NUCLEI
MATERIALS
MINERALS
NUCLEI
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
RARE EARTH COMPLEXES
STABLE ISOTOPES
TRACER TECHNIQUES
YTTERBIUM COMPLEXES
ZEOLITES