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/sup 230/Th-/sup 234/U dating of pedogenic carbonates in gravelly desert soils of Vidal Valley, southeastern California

Journal Article · · Geol. Soc. Am., Bull.; (United States)
 [1]; ; ;
  1. Univ. of Southern California, Los Angeles

Radioactive disequilibrium relationships among /sup 230/Th, /sup 234/U, and /sup 238/U can be used to date pedogenic carbonates formed in regions of arid to semiarid climate. Samples suitable for dating consist of dense carbonate rinds around pebbles from the Cca soil horizon. Analytically, the method involves leaching the samples with dilute hydrochloric acid and measuring /sup 238/C, /sup 234/U, /sup 230/Th, and /sup 232/Th in both the leachate and residue fractions. As the soil carbonate commonly incorporates silicate mineral-bearing detritus, corrections are made to account for possible introduction of detrital /sup 230/Th and /sup 234/U into the acid leachate. The corrections are based on the assumptions that the carbonate initially contains negligible amounts of /sup 232/Th and /sup 230/Th, or has a /sup 230/Th//sup 232/Th ratio similar to that in detrital minerals; /sup 238/U, /sup 234/U, and /sup 230/Th in the detrital silicate phase are in secular equilibrium with each other; and the thorium isotopes in the detrital phase are not fractionated by the acid leaching. Application of the method to calcareous soils developed on upper Quaternary alluvial deposits of the eastern Mojave Desert in southern California gives ages that are internally consistent and that agree with the geomorphic and stratigraphic relative age relationships. Fourteen samples from an upper Pleistocene geomorphic surface, Q2b, yielded an average age of 83,000 +- 10,000 y. This age is confirmed by a different assessment of the data. On one specimen two different layers of a pebble coating were dated, and a carbonate accumulation rate of about 1 mm/8000 y was obtained. 6 figures, 7 tables.

OSTI ID:
6523432
Journal Information:
Geol. Soc. Am., Bull.; (United States), Journal Name: Geol. Soc. Am., Bull.; (United States) Vol. 90:2; ISSN BUGMA
Country of Publication:
United States
Language:
English