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Application of the advanced adiabatic approach to charge exchange in slow collisions between H and O[sup 8+]

Journal Article · · Physical Review A; (United States)
 [1];  [2]
  1. Fakultaet fuer Physik, Hermann-Herder-Strasse 3, 7800 Freiburg (Germany)
  2. Department of Theoretical Physics, St. Petersburg University, St. Petersburg (Russian Federation)
We study charge exchange in slow atomic collisions within the framework of the advanced adiabatic approach [Grozdanov and Solov'ev, Phys. Rev. A 42, 2703 (1990)]. In this approach, nonadiabatic transitions near hidden or avoided crossings are related to branch points connecting adiabatic potential curves at complex values of the internuclear distance. A program package has been developed that automatically takes into account all relevant nonadiabatic transition amplitudes for the calculation of charge-transfer cross sections. The present method allows the inclusion of a large number of molecular-orbital basis functions and turns out to be extremely fast. As an example, partial and total cross sections are calculated for charge exchange in slow O[sup 8+]+H(1[ital s]) collisions. The results are compared to previous theoretical and experimental data.
OSTI ID:
6520376
Journal Information:
Physical Review A; (United States), Journal Name: Physical Review A; (United States) Vol. 48:1; ISSN 1050-2947; ISSN PLRAAN
Country of Publication:
United States
Language:
English