Complexes containing a C sub 2 bridge between an electron-rich metal and an electron-deficient metal. An agostic interaction in a RuCH sub 2 CH sub 2 Zr moiety
Journal Article
·
· Journal of the American Chemical Society; (USA)
- Brookhaven National Lab., Upton, NY (USA)
Complexes containing two metals of disparate electronic properties often exhibit unusual structural and reactivity features. Examples of such compounds include those in which early and late transition metals are joined by a direct metal-metal bond, a bridging CH{sub 2} ligand, or a single carbon atom ({mu}{sub 2}-carbide). The authors report here the preparation of compounds which contain CH{double bond}CH and CH{sub 2}CH{sub 2} bridges between an electron-rich (C{sub 5}H{sub 5})(PMe{sub 3}){sub 2}Ru fragment and an electron-deficient (C{sub 5}H{sub 5}){sub 2}ZrCl moiety.
- DOE Contract Number:
- AC02-76CH00016
- OSTI ID:
- 6519597
- Journal Information:
- Journal of the American Chemical Society; (USA), Vol. 112:8; ISSN 0002-7863
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
RUTHENIUM COMPLEXES
SYNTHESIS
ZIRCONIUM COMPLEXES
DATA ANALYSIS
EXPERIMENTAL DATA
MEASURING METHODS
REACTIVITY
STRUCTURAL CHEMICAL ANALYSIS
COMPLEXES
DATA
INFORMATION
NUMERICAL DATA
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
RUTHENIUM COMPLEXES
SYNTHESIS
ZIRCONIUM COMPLEXES
DATA ANALYSIS
EXPERIMENTAL DATA
MEASURING METHODS
REACTIVITY
STRUCTURAL CHEMICAL ANALYSIS
COMPLEXES
DATA
INFORMATION
NUMERICAL DATA
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties