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Title: Modeling freckle formation in three dimensions during solidification of multicomponent alloys

Journal Article · · Metallurgical and Materials Transactions B: Process Metallurgy and Materials Processing Science
 [1]; ;  [2]
  1. Centro Atomic Bariloche (Argentina)
  2. Univ. of Arizona, Tucson, AZ (United States)

The formation of macrosegregation defects known as freckles was simulated using a three-dimensional finite element model that calculates the thermosolutal convection and macrosegregation during the dendritic solidification of multicomponent alloys. A recently introduced algorithm was used to calculate the complicated solidification path of alloys of many components, which can accommodate liquidus temperatures that are general functions of liquid concentrations. The calculations are started from an all-liquid state, and the growth of the mushy zone is followed in time. Simulations are started from an all-liquid state, and the growth of the mushy zone is followed in time. Simulations of a Ni-Al-Ta-W alloy were performed on a rectangular cylinder until complete solidification. The results reveal details of the formation of freckles not previously observed in two-dimensional simulations. Liquid plumes in the form of chimney convection emanate from channels within the mushy zone, with similar qualitative features previously observed in transparent systems. Associated with the formation of channels, there is a complex three-dimensional flow produced by the interaction of the different solutal buoyancies of the alloy solutes. Regions of enhanced solid growth develop around the channel mouths, which are visualized as volcanoes on top of the mushy zone. The prediction of volcanoes differs from previous calculations with multicomponent alloys in two dimensions, in which the volcanoes were not nearly as apparent. These and other features of freckle formation phenomena are illustrated.

Sponsoring Organization:
USDOE
OSTI ID:
651077
Journal Information:
Metallurgical and Materials Transactions B: Process Metallurgy and Materials Processing Science, Vol. 29, Issue 4; Other Information: PBD: Aug 1998
Country of Publication:
United States
Language:
English