Partial valence trapping in a trinuclear mixed-valence iron(III,III,II) cluster: vibrational spectra of (Fe/sub 3/O(OOCCH/sub 3/)/sub 6/L/sub 3/) and related mixed-metal complexes
Journal Article
·
· J. Am. Chem. Soc.; (United States)
Infrared spectra (800-130 cm/sup -1/) of the mixed-metal and mixed-valence complexes (Fe/sub 2//sup III/M/sup II/O(OOCCH/sub 3/)/sub 6/L/sub 3/) (M = Mn, Fe, Co, Ni; L = H/sub 2/O, pyridine), and Raman spectra of the aquo-adducts, are reported and assigned by using a variety of isotopic substitutions. It is concluded that in the mixed-valence complexes (M = Fe) the oxidation states are partially localized on the vibrational time scale.
- Research Organization:
- Univ. of East Anglia, Norwich, England
- OSTI ID:
- 6509772
- Journal Information:
- J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 109:7; ISSN JACSA
- Country of Publication:
- United States
- Language:
- English
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Valence trapping of mixed-valence (Fe sub 3 O(O sub 2 CCH sub 3 ) sub 6 (py) sub 3 )ter dot S (S = solvent) complexes at high pressure
Journal Article
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Wed May 02 00:00:00 EDT 1984
· J. Am. Chem. Soc.; (United States)
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OSTI ID:6823240
Mixed ruthenium-rhodium trinuclear complex (Ru/sub 2/Rh(. mu. /sub 3/-O)(. mu. -CH/sub 3/COO)/sub 6/(L)/sub 3/)/sup +/ (L = H/sub 2/O or pyridine)
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Valence trapping of mixed-valence (Fe sub 3 O(O sub 2 CCH sub 3 ) sub 6 (py) sub 3 )ter dot S (S = solvent) complexes at high pressure
Journal Article
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Wed May 01 00:00:00 EDT 1991
· Inorganic Chemistry; (United States)
·
OSTI ID:5942516
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ADDUCTS
AZINES
COBALT COMPLEXES
COMPLEXES
CRYSTAL STRUCTURE
DATA
ENERGY LEVELS
EXCITED STATES
EXPERIMENTAL DATA
HETEROCYCLIC COMPOUNDS
HYDRATES
INFORMATION
INFRARED SPECTRA
IRON COMPLEXES
LASER SPECTROSCOPY
MANGANESE COMPLEXES
MOLECULAR STRUCTURE
NICKEL COMPLEXES
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PYRIDINES
RAMAN SPECTROSCOPY
SPECTRA
SPECTROSCOPY
TRANSITION ELEMENT COMPLEXES
VALENCE
VIBRATIONAL STATES
400201* -- Chemical & Physicochemical Properties
ADDUCTS
AZINES
COBALT COMPLEXES
COMPLEXES
CRYSTAL STRUCTURE
DATA
ENERGY LEVELS
EXCITED STATES
EXPERIMENTAL DATA
HETEROCYCLIC COMPOUNDS
HYDRATES
INFORMATION
INFRARED SPECTRA
IRON COMPLEXES
LASER SPECTROSCOPY
MANGANESE COMPLEXES
MOLECULAR STRUCTURE
NICKEL COMPLEXES
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PYRIDINES
RAMAN SPECTROSCOPY
SPECTRA
SPECTROSCOPY
TRANSITION ELEMENT COMPLEXES
VALENCE
VIBRATIONAL STATES