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Comparison of three work of adhesion measurements

Technical Report ·
DOI:https://doi.org/10.2172/650282· OSTI ID:650282
; ;  [1];  [2]
  1. Sandia National Labs., Albuquerque, NM (United States). Dept. of Organic Materials
  2. Case Western Reserve Univ., Cleveland, OH (United States). Dept. of Macromolecular Science

Practical work of adhesion measurements are being studied for several types of polymer/metal combinations in order to obtain a better understanding of the adhesive failure mechanisms for systems containing encapsulated and bonded components. The primary question is whether studies of model systems can be extended to systems of technological interest. The authors report on their first attempts to obtain the work of adhesion between a PDMS polymer and stainless steel. The work of adhesion measurements were made using three techniques -- contact angle, adhesive fracture energy at low deformation rates and JKR. Previous work by Whitesides` group show a good correlation between JKR and contact angle measurements for PDMS. Their initial work focused on duplicating the PDMS measurements of Chaudury. In addition, in this paper the authors extend the work of adhesion measurement to third technique -- interfacial failure energy. The ability to determine the reversible work of adhesion for practical adhesive joints allows understanding of several issues that control adhesion: surface preparation, nature of the interphase region, and bond durability.

Research Organization:
Sandia National Labs., Albuquerque, NM (United States)
Sponsoring Organization:
USDOE Office of Financial Management and Controller, Washington, DC (United States)
DOE Contract Number:
AC04-94AL85000
OSTI ID:
650282
Report Number(s):
SAND--98-0617C; CONF-980222--; ON: DE98003341; BR: YN0100000
Country of Publication:
United States
Language:
English

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