Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Geochemistry of polycyclic aromatic hydrocarbons in Columbia River and Washington coastal sediments

Thesis/Dissertation ·
OSTI ID:6502393

A field investigation was conducted to determine the origins, dispersal pathways and fates of polycyclic aromatic hydrocarbons (PAH) in a river-influenced coastal marine environment. The complex PAH mixtures found in Washington coastal sediments are derived from several land-based sources. PAH products from anthropogenic combustion processes and two natural PAH, retene and perylene, are the dominant components of these complex mixtures. A natural series of phenanthrene homologs and series of tetracyclic PAH geochemically analogous to retene are present as minor constituents. The three major PAH types in Washington coastal sediments are enriched in a narrow band of coarse silt sediment, extending northwestward from the river mouth to Quinault canyon. The natural phenanthrene series is preferentially advected offshore and deposited. These distributions are consistent with known PAH-particle associations and transport processes influencing sediment dispersal in this coastal environment. Dated sediment core records suggest this PAH dispersal pattern has persisted for at least the past century.

OSTI ID:
6502393
Country of Publication:
United States
Language:
English